Unemployed rhymes with:
employed, employed, underemployed, deployed, employed, redeployed, underemployed, bloyd, cloyd, deployed, employed, floyd, gloyd, lloyd, loyd, redeployed, underemployed
Unemployed sounds like:
umfleet, umphlett, unaffiliate, unaffiliated, unbolt, unbolted, unbuilt, unfilled, unfold, unfolded, unveiled