Unemploy rhymes with:
underemploy, employ, underemploy, deploy, employ, ploy, redeploy, underemploy, cloy, deploy, employ, floy, loy, loye, malloy, mccloy, ploy, polloi, redeploy, underemploy
Unemploy sounds like:
umbel, umble, unable, unenviable, unhappily, unifil, unpayable, unveil, unwinnable